Home Chemistry Alcohol, Phenol and Ether General Phenyl methyl ether (anisole) reacts with HI…
Chemistry Alcohol, Phenol and Ether General Single Correct MCQ
Published on: August 14, 2026

Phenyl methyl ether (anisole) reacts with HI to give phenol and methyl iodide and not iodobenzene and methyl alcohol because

A
ion prefers to combine with smaller group in order to minimize steric hindrance
B
ion is not reactive towards benzene
C
Phenol is formed as a result of hydrolysis of iodobenzene
D
Methyl alcohol formed during reaction reacts with to form methyl iodide.

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The correct answer is:
A

In the first step ether gets protonated to from oxonium ion . prefers to combine with smaller group in order to reduce steric hindrance.

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